In the title compound, [Sn(CH 3 ) 2 (C 5 H 10 N 3 S)Cl], the 1isopropylidene-4-methyl-3-thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is s
✦ LIBER ✦
[1,5-Bis(2-hydroxybenzylidene)thiocarbonohydrazide(2–)-κ3S,O,N]dimethyltin(IV)
✍ Scribed by Fang, Xiao-Niu ;Sui, Yan ;Ying, Shao-Ming ;Xu, Ya-Ping ;Guo, Xue-Feng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 359 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [Zn(C 15 H 13 ClN 2 O 2 ) 2 (C 5 H 5 N) 2 ], is a centrosymmetric monomer with octahedral geometry about the Zn atom. The molecule is stabilized by intermolecular CÐ HÁ Á ÁO and CÐHÁ Á ÁCl interactions, so forming a threedimensional network.