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Chiral ruthenium-SDPs/diamine complexes-catalyzed enantioselective hydrogenation of α-alkyl arylacetones via dynamic kinetic resolution

✍ Scribed by Jianhua Xie; Weiling Kong; Xiaocheng Wang; Wenju Bai; Lixin Wang; Qilin Zhou


Book ID
107373710
Publisher
Higher Education Press and Springer
Year
2009
Tongue
English
Weight
176 KB
Volume
4
Category
Article
ISSN
1673-3495

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Enantioselective Synthesis of Chiral β-A
✍ Zhang-Tao Zhou; Jian-Hua Xie; Qi-Lin Zhou 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 1 views

## Abstract magnified image A catalytic enantioselective hydrogenation of racemic α‐aryloxy aldehydes __via__ dynamic kinetic resolution has been developed by using (diamine)(spirodiphosphine)ruthenium(II) chloride [RuCl~2~(SDPs)(diamine)] catalysts. Employing this new reaction system a variety of