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Chiral rhodium(II,II) dimers catalyzed enantioselective intramolecular aziridination of sulfonamides and carbamates

✍ Scribed by Jiang-Lin Liang; Shi-Xue Yuan; Philip Wai Hong Chan; Chi-Ming Che

Book ID: 104254046
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 114 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)01409-6

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✦ Synopsis

The asymmetric intramolecular aziridination of unsaturated sulfonamides and carbamates catalyzed by chiral dirhodium(II,II) complexes were achieved in good yields (up to 95%) and enantioselectivity (up to 76% e.e.).

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