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Rhodium(II)-Catalyzed Aziridination of Allyl-Substituted Sulfonamides and Carbamates

โœ Scribed by Padwa, Albert; Flick, Andrew C.; Leverett, Carolyn A.; Stengel, Thomas


Book ID
115463801
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
197 KB
Volume
69
Category
Article
ISSN
0022-3263

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Chiral rhodium(II,II) dimers catalyzed e
โœ Jiang-Lin Liang; Shi-Xue Yuan; Philip Wai Hong Chan; Chi-Ming Che ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 114 KB

The asymmetric intramolecular aziridination of unsaturated sulfonamides and carbamates catalyzed by chiral dirhodium(II,II) complexes were achieved in good yields (up to 95%) and enantioselectivity (up to 76% e.e.).