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Chiral Rhodium(II,II) Dimers Catalyzed Enantioselective Intramolecular Aziridination of Sulfonamides and Carbamates.

✍ Scribed by Jiang-Lin Liang; Shi-Xue Yuan; Philip Wai Hong Chan; Chi-Ming Che

Publisher: John Wiley and Sons
Year: 2003
Weight: 120 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200347117

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Dedicated to Dr. G¸nther Ohloff on the occasion of his 80th birthday Enantioselective intramolecular amidation of aliphatic sulfonamides was achieved for the first time by means of chiral carboxylatodirhodium(II) catalysts in conjunction with PhI(OAc) 2 and MgO in high yields and with enantioselecti