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Intramolecular Asymmetric Amidations of Sulfonamides and Sulfamates Catalyzed by Chiral Dirhodium(II) Complexes.

✍ Scribed by Corinne Fruit; Paul Mueller


Publisher
John Wiley and Sons
Year
2004
Weight
42 KB
Volume
35
Category
Article
ISSN
0931-7597

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Intramolecular Asymmetric Amidations of
✍ Corinne Fruit; Paul MΓΌller πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 German βš– 180 KB

Dedicated to Dr. GΒΈnther Ohloff on the occasion of his 80th birthday Enantioselective intramolecular amidation of aliphatic sulfonamides was achieved for the first time by means of chiral carboxylatodirhodium(II) catalysts in conjunction with PhI(OAc) 2 and MgO in high yields and with enantioselecti