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ChemInform Abstract: Pd(II)-Catalyzed Enantioselective Intramolecular Heck-Type Reaction to Construct Chiral Sulfonamide Rings.

✍ Scribed by Katsuhiro Akiyama; Koichi Mikami

Publisher: John Wiley and Sons
Year: 2008
Weight: 33 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200823156

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✦ Synopsis

Abstract

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Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy