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Rhodium(II,II) Dimer as an Efficient Catalyst for Aziridination of Sulfonamides and Amidation of Steroids

✍ Scribed by Liang, Jiang-Lin; Yuan, Shi-Xue; Chan, Philip Wai Hong; Che, Chi-Ming

Book ID
118738545
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
83 KB
Volume
4
Category
Article
ISSN
1523-7060

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πŸ“œ SIMILAR VOLUMES

Chiral rhodium(II,II) dimers catalyzed e
Chiral rhodium(II,II) dimers catalyzed enantioselective intramolecular aziridination of sulfonamides and carbamates
✍ Jiang-Lin Liang; Shi-Xue Yuan; Philip Wai Hong Chan; Chi-Ming Che πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 114 KB

The asymmetric intramolecular aziridination of unsaturated sulfonamides and carbamates catalyzed by chiral dirhodium(II,II) complexes were achieved in good yields (up to 95%) and enantioselectivity (up to 76% e.e.).