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Chemistry of carbanions stabilized by sulfur. 1. Chemistry of 1,3-oxathianes. Synthesis and conformation of 2-substituted 1,3-oxathianes

✍ Scribed by Fuji, Kaoru; Ueda, Masaru; Sumi, Kenzo; Kajiwara, Kanji; Fujita, Eiichi; Iwashita, Takashi; Miura, Iwao

Book ID
120027056
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
653 KB
Volume
50
Category
Article
ISSN
0022-3263

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Synthesis of 2-Alkylidene-3,3-dialkyl-1,4-dithianes and Their Oxathiane Analogues by 1,2-Sulfur Migration. -Base-promoted mesylation of tertiary alcohols such as (I) and (III) derived from dithianes or oxathianes results in rearrangement by sulfur migration to yield the 1,4-dithianes (II) and their