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ChemInform Abstract: Synthesis of 2-Alkylidene-3,3-dialkyl-1,4-dithianes and Their Oxathiane Analogues by 1,2-Sulfur Migration.

✍ Scribed by M. T. BARROS; C. D. MAYCOCK; L. S. SANTOS

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of 2-Alkylidene-3,3-dialkyl-1,4-dithianes and Their Oxathiane Analogues by 1,2-Sulfur Migration.

-Base-promoted mesylation of tertiary alcohols such as (I) and (III) derived from dithianes or oxathianes results in rearrangement by sulfur migration to yield the 1,4-dithianes (II) and their oxathiane analogues (IV). -(BARROS, M. T.; MAYCOCK, C. D.;

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