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ChemInform Abstract: Synthesis of Substituted 1,3-Oxathianes and 1,3-Oxathiolanes.

✍ Scribed by SHAMSUZZAMAN SHAMSUZZAMAN; M. ASLAM; A. SALIM; M. K. AKRAM; F. NAQVI

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199836237

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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Stereochemically Controlled Synthesis of Substituted 1,2-Oxathianes. -Treatment of 4-sulfanyl-1,3-diols containing a tertiary SH group with tosyl chloride and triethylamine results in high-yielding cyclization to give 1,2-oxathianes as single diastereomers. Subjecting the sulfanyldiol (IX) to analo