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Conversion of 1,3-Oxathiolanes to 1,4-Oxathianes Using a Silylated Diazoester.

✍ Scribed by Maria Ioannou; Michael J. Porter; Fabienne Saez


Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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Anchimeric Assistance in the Rearrangement of Dichloro-3-methyl-1,4-oxathianes to 2-Chloromethyl Dihydro-1,4-oxathiins. -The synthesis of title oxathiins (VI) by the rearrangement of readily available oxathianes (V) under anchimeric assistance of anilide is described. The inductive effect of the ca