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Chemistry of carbanions stabilized by sulfur. 2. Chemistry of 1,3-oxathianes. Reactivity of 2-heterosubstituted 1,3-oxathianes toward secondary butyllithium and the reaction of 2-(trimethylsilyl)-1,3-oxathianyl anion with electrophiles

โœ Scribed by Fuji, Kaoru; Ueda, Masaru; Sumi, Kenzo; Fujita, Eiichi


Book ID
126816395
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
700 KB
Volume
50
Category
Article
ISSN
0022-3263

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Synthesis of 2-heterosubstituted 1,3-oxa
โœ Kaoru Fuji; Masaru Ueda; Kenzo Sumi; Eiichi Fujita ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

Swmary : A series of 2-heterosubstituted 1,3-oxathianes were synthesized and their reactivity toward a strong base, see-butvllithium, was studied. It was shown that see-butyllithium attacked 2-heterosubstituted 1,3-oxathianes in three different ways depending upon the heteroatom at C-2; the removal