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ChemInform Abstract: Total Synthesis of Brevetoxin A. Part 1. First Generation Strategy and Construction of BCD Ring System.

✍ Scribed by K. C. Nicolaou; Mark E. Bunnage; Daniel G. McGarry; Shuhao Shi; Patricia K. Somers; Paul A. Wallace; Xin-Jie Chu; Konstantinos A. Agrios; Janet L. Gunzner; Zhen Yang

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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Our second generation strategy for the total synthesis of brevetoxin A involved dissection of the molecule at the ring F oxocene. Synthetically, the F ring formation was expected to occur through Wittig coupling of requisite polycyclic fragments 2 and 3, followed by a hydroxy dithioketal cyclization

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