ChemInform Abstract: Synthesis of 1,2,4-Trioxanes and 1,2,4-Trioxepanes by N- Halogenosuccinimide Mediated Cyclizations of Unsaturated Hydroperoxyacetals.
β Scribed by Y. USHIGOE; Y. KANO; M. NOJIMA
- Book ID
- 112042273
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Oxy-functionalized 1,2,4-trioxanes or 1,2,4-trioxepanes were produced by either autoxidation of the unsaturated hydroperoxy acetals 1, or the acid-catalyzed cyclization of epoxy hydroperoxides 9 which were readily prepared from 1. By the appropriate choice of cyclization procedure, the structures of
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