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ChemInform Abstract: Synthesis of 1,2-Dioxanes, 1,2,4-Trioxanes, and 1,2,4-Trioxepanes via Cyclizations of Unsaturated Hydroperoxyacetals.

โœ Scribed by P. H. DUSSAULT; D. R. DAVIES


Book ID
112031545
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Oxy-functionalized 1,2,4-trioxanes or 1,2,4-trioxepanes were produced by either autoxidation of the unsaturated hydroperoxy acetals 1, or the acid-catalyzed cyclization of epoxy hydroperoxides 9 which were readily prepared from 1. By the appropriate choice of cyclization procedure, the structures of