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Synthesis of 1,2-dioxanes, 1,2,4-trioxanes, and 1,2,4-trioxepanes via cyclizations of unsaturated hydroperoxyacetals

โœ Scribed by Patrick H Dussault; Don R Davies


Book ID
103403203
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
220 KB
Volume
37
Category
Article
ISSN
0040-4039

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Oxy-functionalized 1,2,4-trioxanes or 1,2,4-trioxepanes were produced by either autoxidation of the unsaturated hydroperoxy acetals 1, or the acid-catalyzed cyclization of epoxy hydroperoxides 9 which were readily prepared from 1. By the appropriate choice of cyclization procedure, the structures of