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ChemInform Abstract: Asymmetric Synthesis of a C-3 Substituted Pipecolic Acid.

✍ Scribed by Andrew J. Souers; Jonathan A. Ellman


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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ChemInform Abstract: Asymmetric Synthesi
✍ C. AGAMI; D. BIHAN; R. MORGENTIN; C. PUCHOT-KADOURI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

The synthesis of two enantiopure pipecolic acid esters (VI) and (XIII) is reported. Key steps are the intramolecular addition of allyl silane on an iminium double bond, generated via reaction of chiral Ξ²-amino alcohols (I) and (VII), with glyoxal (II).