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ChemInform Abstract: Asymmetric Synthesis of 3-Alkyl Pipecolic Acids.

✍ Scribed by A. Zaparucha; M. Danjoux; A. Chiaroni; J. Royer; H.-P. Husson

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Synthesi
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The synthesis of two enantiopure pipecolic acid esters (VI) and (XIII) is reported. Key steps are the intramolecular addition of allyl silane on an iminium double bond, generated via reaction of chiral Ξ²-amino alcohols (I) and (VII), with glyoxal (II).