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ChemInform Abstract: Asymmetric Syntheses of Enantiopure 4-Substituted Pipecolic Acid Derivatives.

✍ Scribed by Claude Agami; Fabrice Bisaro; Sebastien Comesse; Sebastien Guesne; Catherine Kadouri-Puchot; Remy Morgentin

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Synthesi
ChemInform Abstract: Asymmetric Synthesis of Unsaturated Pipecolic Acid Derivatives.
✍ C. AGAMI; D. BIHAN; R. MORGENTIN; C. PUCHOT-KADOURI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

The synthesis of two enantiopure pipecolic acid esters (VI) and (XIII) is reported. Key steps are the intramolecular addition of allyl silane on an iminium double bond, generated via reaction of chiral Ξ²-amino alcohols (I) and (VII), with glyoxal (II).