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ChemInform Abstract: A Silicon-Mediated Synthesis of 3-Deoxy-D-manno-octulosonic Acid (KDO).

✍ Scribed by Nico Braeuer; Andreas Kirschning; Ernst Schaumann

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199916210

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✦ Synopsis

A Silicon-Mediated Synthesis of 3-Deoxy-D-manno-octulosonic Acid (KDO). -Starting from commercially available D-mannitol (I), the synthesis of KDO ammonium salt (VII) includes, as key steps, a silicon-mediated epoxide ring opening reaction of (II) and silicon-induced lactonization of carbonate (V) with Bu 4

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