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ChemInform Abstract: Total Synthesis of 3-Deoxy-D-manno-2-octulosonic Acid (KDO) and 2-Deoxy-β-KDO.

✍ Scribed by Steven D. Burke; Geoffrey M. Sametz

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
30
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

A Silicon-Mediated Synthesis of 3-Deoxy-
A Silicon-Mediated Synthesis of 3-Deoxy-D-manno-octulosonic Acid (KDO)
✍ Nico Bräuer; Andreas Kirschning; Ernst Schaumann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 2 views

KDO (1) is synthesized in five steps, starting from 1,2-to the carbonate 9. Silicon-induced lactonization affords the lactone 10, which can be converted into NH 4 -KDO by anhydro-3,4:5,6-di-O-isopropylidene-D-mannitol ( 6). The epoxide 6, obtained from D-mannitol (2), reacts with lithiated standard

ChemInform Abstract: A Silicon-Mediated
ChemInform Abstract: A Silicon-Mediated Synthesis of 3-Deoxy-D-manno-octulosonic Acid (KDO).
✍ Nico Braeuer; Andreas Kirschning; Ernst Schaumann 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

A Silicon-Mediated Synthesis of 3-Deoxy-D-manno-octulosonic Acid (KDO). -Starting from commercially available D-mannitol (I), the synthesis of KDO ammonium salt (VII) includes, as key steps, a silicon-mediated epoxide ring opening reaction of (II) and silicon-induced lactonization of carbonate (V) w