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Chemically induced dynamic nuclear polarization during thermal decomposition of peroxides and azo compounds

✍ Scribed by Fischer, Hanns; Bargon, Joachim


Book ID
127285291
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
634 KB
Volume
2
Category
Article
ISSN
0001-4842

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Chemically Induced Dynamic Nuclear Polar
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## Abstract Thermolysis of di‐(4‐chlorobenzoyl)‐peroxide was carried out in the probe of an NMR. spectrometer. The dependence of product distribution and chemically induced dynamic nuclear polarization (CIDNP.) patterns on the concentrations of radical trapping agents gives evidence that the CIDNP.

Chemically induced dynamic nuclear polar
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## Carbon-13 NNR spectra of chemically polarized decomposition pro&&s %%X6? in~est~g~~~d. The pofarization is much larger than in proton spectra, positive for radical recombination pro&cts and negative Ear thr? others. The chemical polarization appears ;IC the very moment of Formation of the stabl