✦ LIBER ✦

Chemically induced dynamic nuclear polarization of 13C nuclei in the thermal decomposition of organic peroxides

✍ Scribed by E. Lippmaa; T. Pehk; A.L. Buchachenko; S.V. Rykov

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 532 KB
Volume: 5
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)85125-9

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✦ Synopsis

Carbon-13

NNR spectra of chemically polarized decomposition pro&&s %%X6? in~est~g~~~d. The pofarization is much larger than in proton spectra, positive for radical recombination pro&cts and negative Ear thr? others. The chemical polarization appears ;IC the very moment of Formation of the stable reaction prad--_ ucts.

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