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Chemically induced nuclear polarization in the thermal decomposition of benzoyl and acetylbenzoyl peroxides in the presence of iodides

✍ Scribed by S. V. Rykov; A. V. Kessenikh; A. V. Ignatenko


Book ID
112437681
Publisher
Springer
Year
1975
Tongue
English
Weight
241 KB
Volume
24
Category
Article
ISSN
1573-9171

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## Carbon-13 NNR spectra of chemically polarized decomposition pro&&s %%X6? in~est~g~~~d. The pofarization is much larger than in proton spectra, positive for radical recombination pro&cts and negative Ear thr? others. The chemical polarization appears ;IC the very moment of Formation of the stabl

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## Abstract Thermolysis of di‐(4‐chlorobenzoyl)‐peroxide was carried out in the probe of an NMR. spectrometer. The dependence of product distribution and chemically induced dynamic nuclear polarization (CIDNP.) patterns on the concentrations of radical trapping agents gives evidence that the CIDNP.