Chemically induced dynamic nuclear polarization. XI. Thermal decomposition of acetyl peroxide
β Scribed by Kaptein, R.; Brokken-Zijp, J.; De Kanter, F. J. J.
- Book ID
- 127186101
- Publisher
- American Chemical Society
- Year
- 1972
- Tongue
- English
- Weight
- 867 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Thermolysis of diβ(4βchlorobenzoyl)βperoxide was carried out in the probe of an NMR. spectrometer. The dependence of product distribution and chemically induced dynamic nuclear polarization (CIDNP.) patterns on the concentrations of radical trapping agents gives evidence that the CIDNP.
## Carbon-13 NNR spectra of chemically polarized decomposition pro&&s %%X6? in~est~g~~~d. The pofarization is much larger than in proton spectra, positive for radical recombination pro&cts and negative Ear thr? others. The chemical polarization appears ;IC the very moment of Formation of the stabl