Chain Length Dependence of Radical−Radical Termination in Free Radical Polymerization: A Pulsed Laser Photolysis Investigation
✍ Scribed by Shipp, Devon A.; Solomon, David H.; Smith, Trevor A.; Moad, Graeme
- Book ID
- 127215161
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 153 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The technique of SPPLP EPR, which is single‐pulse pulsed‐laser polymerization (SPPLP) in conjunction with electron paramagnetic resonance (EPR) spectroscopy, is used to carry out a detailed investigation of secondary (chain‐end) radical termination of acrylates. Measurements are perform
## Abstract **Summary:** A novel method combining RAFT polymerization with pulsed‐laser initiation for determining chain‐length dependent termination rate coefficients, __k__~t~, is presented. Degenerative chain‐transfer in RAFT enables single‐pulse pulsed‐laser polymerization (SP‐PLP) traces to be