✦ LIBER ✦

Chain-length dependence of free-radical termination rate deduced from laser single-pulse experiments

✍ Scribed by Michael Buback; Markus Busch; Christopher Kowollik

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 161 KB
Volume: 9
Category: Article
ISSN: 1022-1344
DOI: 10.1002/1521-3919(20001101)9:8<442::aid-mats442>3.0.co;2-i

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics of free-radical polymerization

Kinetics of free-radical polymerization with chain-length-dependent constants under initiation by laser pulses: Effect of chain length dependence of propagation

✍ Anatolij N. Nikitin; Alexander V. Evseev 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 216 KB 👁 2 views

A numerical procedure is developed which allows taking into account the chain length dependence of the termination and propagation constants for calculating molecular weight distributions (MWDs) formed under free-radical polymerization initiated by an arbitrary sequence of laser pulses. The law whe

Chain length-dependent termination in pu

Chain length-dependent termination in pulsed-laser polymerization. VIII. The temperature dependence of the rate coefficient of bimolecular termination in the bulk polymerization of styrene

✍ Oskar Friedrich Olaj; Philipp Vana 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB 👁 2 views

The photosensitized polymerization of styrene in bulk was investigated in the temperature range of 25-70°C with respect to the average rate coefficient of bimolecular chain termination k t , especially its chain length dependence at low conversions, by means of pulsed laser polymerization (PLP). Thr

Chain-length dependent termination in pu

Chain-length dependent termination in pulsed-laser polymerization, 7. The evaluation of the power-law exponent b from the chain-length distribution in the low frequency (single-pulse) limit for the reference systems styrene and methyl methacrylate in bulk at 25°C

✍ Oskar Friedrich Olaj; Philipp Vana; Andreas Kornherr; Gerhard Zifferer 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 124 KB 👁 2 views