Chain-Length-Dependent Termination in Acrylate Radical Polymerization Studied via Pulsed-Laser-Initiated RAFT Polymerization
✍ Scribed by Buback, Michael; Hesse, Pascal; Junkers, Thomas; Theis, Thomas; Vana, Philipp
- Book ID
- 121334570
- Publisher
- Commonwealth Scientific and Industrial Research Organisation Publishing
- Year
- 2007
- Tongue
- English
- Weight
- 421 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0004-9425
- DOI
- 10.1071/CH07236
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📜 SIMILAR VOLUMES
## Abstract **Summary:** A novel method combining RAFT polymerization with pulsed‐laser initiation for determining chain‐length dependent termination rate coefficients, __k__~t~, is presented. Degenerative chain‐transfer in RAFT enables single‐pulse pulsed‐laser polymerization (SP‐PLP) traces to be
## Abstract The technique of SPPLP EPR, which is single‐pulse pulsed‐laser polymerization (SPPLP) in conjunction with electron paramagnetic resonance (EPR) spectroscopy, is used to carry out a detailed investigation of secondary (chain‐end) radical termination of acrylates. Measurements are perform
## Abstract Using a new simulation procedure in which each individual propagation step is subjected to a Poisson process it was proved that in case of chain‐length dependent termination the apparent rate of propagation no longer coincides with the true one. This is caused by the polydispersity of t