Chain Length Dependent Termination in Butyl Acrylate Free-Radical Polymerization Studied via Stationary and Pulsed Laser Initiated RAFT Polymerization
✍ Scribed by Junkers, Thomas; Theis, Alexander; Buback, Michael; Davis, Thomas P.; Stenzel, Martina H.; Vana, Philipp; Barner-Kowollik, Christopher
- Book ID
- 120630334
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 258 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
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## Abstract **Summary:** A novel method combining RAFT polymerization with pulsed‐laser initiation for determining chain‐length dependent termination rate coefficients, __k__~t~, is presented. Degenerative chain‐transfer in RAFT enables single‐pulse pulsed‐laser polymerization (SP‐PLP) traces to be
Abstraet~Calculations on non-classical systems of the type mentioned in the title have been carried out 'iJsing the treatment described in Part I. As before chain transfer has been neglected. It is shown that the properties of the total pre-effect AMpr ~ are analogous to those previously deduced for