Chain-length-dependent termination for free radical polymerization
โ Scribed by Zhu, S.; Hamielec, A. E.
- Book ID
- 126002620
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 680 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The technique of SPPLP EPR, which is singleโpulse pulsedโlaser polymerization (SPPLP) in conjunction with electron paramagnetic resonance (EPR) spectroscopy, is used to carry out a detailed investigation of secondary (chainโend) radical termination of acrylates. Measurements are perform
A~traet A numeric solution is developed for a kinetic scheme involving chain length dependent termination (by disproportionation) and chain transfer on the basis of the harmonic and the geometric mean approximation for the two radicals involved in the termination process. In addition, solutions in t