Kinetics of Free-Radical Polymerization with Chain-Length-Dependent Bimolecular Termination under Unstationary Conditions
β Scribed by Tobita, Hidetaka
- Book ID
- 126072970
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 679 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A numerical procedure is developed which allows taking into account the chain length dependence of the termination and propagation constants for calculating molecular weight distributions (MWDs) formed under free-radical polymerization initiated by an arbitrary sequence of laser pulses. The law whe
A~traet A numeric solution is developed for a kinetic scheme involving chain length dependent termination (by disproportionation) and chain transfer on the basis of the harmonic and the geometric mean approximation for the two radicals involved in the termination process. In addition, solutions in t
## Abstract Kinetic simulations using the composite __k__~t~ model allows a better understanding of the effects of the persistent radical affecting ATRP or for that matter any activationβdeactivation system. It also provides a better fit to experimental data in either bulk or solution conditions fo