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Bis(μ-thio­phene-2-carbaldehyde thio­semicarbazonato)bis­[acetonitrile­copper(I)] bis­(tetra­fluoro­borate)

✍ Scribed by Pike, Robert D. ;Wiles, Austin B. ;Tronic, Tristan A.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
159 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu 2 (C 6 H 7 N 3 S 2 ) 2 (C 2 H 3 N) 2 ](BF 4 ) 2 , is a dimer with a central Cu 2 S 2 core resulting from thiosemicarbazone sulfur bridging. Both Cu-TCT units (TCT is the thiophene-2-carboxaldehyde thiosemicarbazone anion) are roughly planar and are parallel to one another and perpendicular to the Cu 2 S 2 plane.

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Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.005 A Ê R factor = 0.035 wR factor = 0.092 Data-to-parameter ratio = 13.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.