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Bis­[μ-1,3-bis­(di­phenyl­phosphino)­propane]­disilver(I) bis­(tetra­fluoro­borate)

✍ Scribed by Smith, Michele L. ;Almond, Philip M. ;Albrecht-Schmitt, Thomas E. ;Hill, William E.


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
128 KB
Volume
59
Category
Article
ISSN
1600-5368

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Bis­[μ-bis­(di­phenyl­phosphino)­methane
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.026 A Ê R factor = 0.066 wR factor = 0.160 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis­[μ-bis­(di­phenyl­phosphino)­methane
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The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.