Bis[μ-1,3-bis(diphenylphosphino)propane]disilver(I) bis(tetrafluoroborate)
✍ Scribed by Smith, Michele L. ;Almond, Philip M. ;Albrecht-Schmitt, Thomas E. ;Hill, William E.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 128 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.026 A Ê R factor = 0.066 wR factor = 0.160 Data-to-parameter ratio = 14.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cu 2 (" 2 -dppm) 2 (MeCN) 4 ](PF 6 ) 2 or [Cu 2 (C 25 H 22 P 2 ) 2 (C 2 H 3 N) 4 ](PF 6 ) 2 , crystallizes in the monoclinic space group C2/c, with the cation on a twofold axis. The Cu centers are four-coordinated, exhibiting pseudo-tetrahedral coordination.
Acta Cryst. (2003). E59, m273±m275 atoms at distances of ca 3.5 A Ê . The cations and anions exist as discrete entities in the unit cell (Fig. 3).