The title compound, [Cu 2 (C 6 H 7 N 3 S 2 ) 2 (C 2 H 3 N) 2 ](BF 4 ) 2 , is a dimer with a central Cu 2 S 2 core resulting from thiosemicarbazone sulfur bridging. Both Cu-TCT units (TCT is the thiophene-2-carboxaldehyde thiosemicarbazone anion) are roughly planar and are parallel to one another and
Bis(pyridine-2-carbaldehyde thiosemicarbazonato)cobalt(III) perchlorate
✍ Scribed by Wang, Heng-Shan ;Huang, Ling ;Chen, Zhen-Feng ;Wang, Xian-Wen ;Zhou, Jian ;Shi, Shao-Ming ;Liang, Hong ;Yu, Kai-Bei
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 265 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.005 A Ê R factor = 0.035 wR factor = 0.092 Data-to-parameter ratio = 13.0
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.081 wR factor = 0.177 Data-to-parameter ratio = 15.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Co(C 31 H 31 N 7 )](ClO 4 ) 2 .0.365H 2 O, contains a high-spin Co II atom which is coordinated by seven N atoms at the corners of a distorted pentagonal bipyramid.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê Disorder in solvent or counterion R factor = 0.075 wR factor = 0.213 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.