Bis{[tris(1H-benzimidazol-2-ylmethyl)amine]chlorocobalt(II)} tetrachlorocobaltate(II) methanol tetrasolvate
✍ Scribed by Li, Xue-Mei ;Feng, Si-Si ;Zhang, Hong-Mei ;Su, Ying-Lan ;Qin, Shi-Dong ;Lu, Li-Ping ;Xue, Wan-Hua ;Zhu, Miao-Li
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 357 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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Acetoacetylferrocene reacted with cobalt chloride and tris(2-aminoethyl)amine in methanol to give the title complex, [CoFe(C~5~H~5~)(C~9~H~8~O~2~)(C~6~H~18~N~4~)](C~24~H~20~B)Cl·C~3~H~6~O, with acetoacetylferrocene and a tripod amine as ligands. The Co atom has slightly distorted octahedral coordina
In the title structure, [Cu(C~24~H~21~N~7~)(H~2~O)](ClO~4~)~2~·C~5~H~4~N~2~O~3~·H~2~O, the Cu^II^ atom is bonded to a tris(1__H__-benzimidazol-2-ylmethyl)amine (ntb) ligand and a water molecule through four N atoms and one O atom, giving a distorted trigonal–bipyramidal coordination geometry with ap
The title complex, (C 6 H 18 N 2 )[V 2 Cl 5 (C 6 H 16 N 2 ) 2 ](C 24 H 20 B).-C 4 H 8 O, was prepared by the reaction of [V 2 Cl 3 (THF) 6 ](BPh 4 ) with [FeCl 2 (tmeda) 2 ] in the presence of one equivalent of tmeda (tmeda = N,N,N H ,N H -tetramethylethylenediamine) in methanol. The crystal structu