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Aqua­[tris­(1H-benzimidazol-2-ylmeth­yl)amine]copper(II) bis­(perchlorate) 4-nitro­pyridine N-oxide monohydrate

✍ Scribed by Wu, Hui-Lu ;Dong, Wen-Kui ;Chen, Ying

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
266 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title structure, Cu(C~24~H~21~N~7~)(H~2~O)~2~·C~5~H~4~N~2~O~3~·H~2~O, the Cu^II^ atom is bonded to a tris(1__H__-benzimidazol-2-ylmethyl)amine (ntb) ligand and a water molecule through four N atoms and one O atom, giving a distorted trigonal–bipyramidal coordination geometry with approximate C
~3~ molecular symmetry.

📜 SIMILAR VOLUMES

(4-Hydroxy­cinnamato)[tris­(N-methyl­ben
(4-Hydroxy­cinnamato)[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide hemisolvate
✍ Wu, Hui-Lu ;Ma, Xing-Ke ;Lv, Wei-Bing ;Liu, Peng ;Liu, Ji-Gang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 364 KB

In the title complex, [Cu(C~9~H~7~O~3~)(C~27~H~27~N~7~)]ClO~4~·0.5C~3~H~7~NO, the Cu^II^ ion five-coordinate with an N~4~O ligand set and has a distorted trigonal–bipyramidal geometry.

(2-Methacrylato)[tris(1-methyl-1H-benzim
(2-Methacrylato)[tris(1-methyl-1H-benzimidazol-2-ylmethyl)amine]copper(II) perchlorate dimethylformamide disolvate hemihydrate at 153 (2) K
✍ Wu, Huilu ;Ying, Wei ;Ding, Jian ;Yuan, Jingkun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 925 KB

In the title complex, [Cu(C 4 H 5 O 2 )(C 27 H 27 N 7 )](ClO 4 )Á-2C 3 H 7 NOÁ0.5H 2 O, the Cu II ion is five-coordinated by four N atoms from a tris(N-methylbenzimidazol-2-ylmethyl)amine ligand and one O atom from a 2-methacrylate ligand in a distorted trigonal-bipyramidal geometry with approximate