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(4-Hydroxy­cinnamato)[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]copper(II) perchlorate dimethyl­formamide hemisolvate

✍ Scribed by Wu, Hui-Lu ;Ma, Xing-Ke ;Lv, Wei-Bing ;Liu, Peng ;Liu, Ji-Gang

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
364 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Cu(C~9~H~7~O~3~)(C~27~H~27~N~7~)]ClO~4~·0.5C~3~H~7~NO, the Cu^II^ ion five-coordinate with an N~4~O ligand set and has a distorted trigonal–bipyramidal geometry.

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In the title complex, [Cu(C 4 H 5 O 2 )(C 27 H 27 N 7 )](ClO 4 )Á-2C 3 H 7 NOÁ0.5H 2 O, the Cu II ion is five-coordinated by four N atoms from a tris(N-methylbenzimidazol-2-ylmethyl)amine ligand and one O atom from a 2-methacrylate ligand in a distorted trigonal-bipyramidal geometry with approximate

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Bis[l-bis(4-nitrophenyl)phosphato-j 2 O:O 0 0 0 ]bis{[bis(2pyridylmethyl)amine-j 3 N,N 0 0 0 ,N 0 0 00 0 00 0 0 ]copper(II)} diperchlorate acetonitrile hemisolvate

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Synthesis and Characterization of Copper Complexes Containing the Tripodal N7 Ligand Tris{2-[(pyridin-2-ylmethyl)amino]ethyl}amine (=N′-(Pyridin-2-ylmethyl)-N,N-bis{2-[(pyridin-2-ylmethyl)amino]ethyl}ethane-1,2-diamine): Equilibrium, Spectroscopic Data, and Crystal Structures of Mono- and Trinuclear Copper(II) Complexes
✍ Christian Gérard; Aminou Mohamadou; Jérôme Marrot; Stéphane Brandes; Alain Tabar 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 201 KB 👁 2 views

## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t