In the title complex, [Ni(C 16 H 22 N 6 ) 2 ]Br 2 , the Ni atom is in a slightly distorted octahedral coordination environment, having crystallographic 2/m symmetry. The Ni atom is coordinated by the six pyrazolyl rings of the two tridentate tris(3,5-dimethylpyrazolyl)methane ligands, with Ni-N dist
[Bis[tris(3,5-dimethylpyrazolyl)methane]nickel(II)][tetrachloronickelate(II)]–methanol–water (1/1/1)
✍ Scribed by Michaud, Annie ;Fontaine, Frédéric-Georges ;Zargarian, Davit
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 185 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [CuCl~2~(C~11~H~16~N~4~)], is isostructural with the previously characterized Zn^II^ analogous complex. The Cu^II^ ion is four-coordinate in a CuCl~2~N~2~ distorted tetrahedral geometry. In the crystal structure, weak C—H...Cl interactions are observed.
In the title compound, [Cd(C 11 H 9 ClN 3 O 2 ) 2 ]Á4H 2 O, the Cd II atom is coordinated by four N atoms and two O atoms from two picolinate ligands in a distorted octahedral geometry. In the crystal structure, molecules are linked together by intermolecular O-HÁ Á ÁO hydrogen bonds. Related litera