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Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato]cadmium(II) tetrahydrate

✍ Scribed by Zhao, Kai ;Yin, Xian-Hong ;Feng, Yu ;Zhu, Jie

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 632 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807055857

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✦ Synopsis

In the title compound, [Cd(C 11 H 9 ClN 3 O 2 ) 2 ]Á4H 2 O, the Cd II atom is coordinated by four N atoms and two O atoms from two picolinate ligands in a distorted octahedral geometry. In the crystal structure, molecules are linked together by intermolecular O-HÁ Á ÁO hydrogen bonds. Related literature For related literature, see: Bhatia et al. (1981); Costamagna et al. (1992).

Experimental Crystal data [Cd(C 11 H 9 ClN 3 O 2 ) 2 ]Á4H 2 O M r = 685.79 Triclinic, P1 a = 10.1790 (10) A b = 11.4140 (14) A c = 13.4240 (18) A = 114.745 (3) = 102.249 (2) = 96.4280 (10) V = 1348.3 (3) A ˚3 Z = 2 Mo K radiation = 1.07 mm À1 T = 298 (2) K 0.51 Â 0.50 Â 0.48 mm Data collection Bruker SMART CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T min = 0.613, T max = 0.629 6989 measured reflections 4645 independent reflections 3752 reflections with I > 2(I) R int = 0.020 Refinement R[F 2 > 2(F 2 )] = 0.037 wR(F 2 ) = 0.101 S = 1.05 4645 reflections

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