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Bis(O,O′-di­cyclo­hexyl di­thio­phosphato-κ2S,S′)­platinum(II)

✍ Scribed by Kuan, Fong Sheen ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
188 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.009 A Ê R factor = 0.034 wR factor = 0.085 Data-to-parameter ratio = 28.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

📜 SIMILAR VOLUMES

μ-1,4-Diaza­bicyclo­[2.2.2]octane-κ2N:N′
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The dinuclear title molecule, [Cd~2~(C~12~H~22~O~2~PS~2~)~4~(C~6~H~12~N~2~)], is disordered and located on a centre of inversion, and features a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal.

catena-Poly[[bis­(O,O′-dicyclo­hexyl dit
catena-Poly[[bis­(O,O′-dicyclo­hexyl dithiophos­phato-κ2S,S′)nickel(II)]-μ-4,4′-bipyridine-κ2N:N′]
✍ Berdugo, Erick ;Tiekink, Edward R. T. ;Wardell, James L. ;Wardell, Solange M. S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 462 KB

The Ni atom in the linear polymeric title complex, [Ni{S~2~P(OC~6~H~11~)~2~}~2~(NC~5~H~4~C~5~H~4~N)]~__n__~ or [Ni(C~12~H~22~O~2~PS~2~)~2~(C~10~H~8~N~2~)]~__n__~, is octahedrally coordinated within a __trans__-N~2~S~4~ donor set. The Ni atom and the N atoms of the 4,4′-bipyridine ligand are located