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Tris(O,O′-dicyclo­hexyl dithio­phosphato-κ2S,S′)bismuth(III) chloro­form disolvate

✍ Scribed by Eey, Stanley Tze Chiang ;Lai, Chian Sing ;Tiekink, Edward R. T.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
718 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

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The dinuclear title molecule, [Cd~2~(C~12~H~22~O~2~PS~2~)~4~(C~6~H~12~N~2~)], is disordered and located on a centre of inversion, and features a coordination geometry intermediate between square-pyramidal and trigonal-bipyramidal.

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The title complex, [Co{S 2 CN(CH 2 ) 4 } 3 ]Á2CHCl 3 , contains Co III octahedrally coordinated by three bidentate dithiocarbamate ligands. Chloroform molecules form C-HÁ Á ÁS interactions with the complex.

catena-Poly[[bis­(O,O′-dicyclo­hexyl dit
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The Ni atom in the linear polymeric title complex, [Ni{S~2~P(OC~6~H~11~)~2~}~2~(NC~5~H~4~C~5~H~4~N)]~__n__~ or [Ni(C~12~H~22~O~2~PS~2~)~2~(C~10~H~8~N~2~)]~__n__~, is octahedrally coordinated within a __trans__-N~2~S~4~ donor set. The Ni atom and the N atoms of the 4,4′-bipyridine ligand are located

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✍ Li, Feng ;Pan, Xian-Xiu ;Yin, Han-Dong ;Zhai, Jun ;Wang, Daqi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 120 KB

Single-crystal X-ray study T = 298 K Mean (C-C) = 0.015 A Disorder in main residue R factor = 0.045 wR factor = 0.119 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.