In the title centrosymmetric mononuclear copper(II) compound, [Cu(C 14 H 22 N 2 O) 2 ](ClO 4 ) 2 , the Cu II atom is coordinated by two N atoms and two O atoms from two Schiff base ligands. The coordination geometry is slightly distorted square-planar. The disordered perchlorate anions are hydrogen
Bis{N′-[(E)-amino(imino)methyl]morpholinocarboximidamido}copper(II)
✍ Scribed by Lu, Liping ;Zhu, Miaoli
- Book ID
- 104481151
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 392 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound, [Cu(C 15 H 14 NO) 2 ], adopts a stepped conformation and displays a square-planar trans-[CuN 2 O 2 ] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the CuÐN and CuÐO bond di
Single-crystal X-ray study T = 183 K Mean '(C±C) = 0.003 A Ê R factor = 0.044 wR factor = 0.121 Data-to-parameter ratio = 25.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Cu(C 9 H 13 N 2 O 2 S) 2 ], is a centrosymmetric neutral complex with the Cu II atom showing slightly distorted square-planar CuN 4 geometry. The crystal packing is consolidated by intramolecular N-HÁ Á ÁO and intermolecular C-HÁ Á Á interactions.
This article reports the retraction of 39 articles published in Acta Crystallographica Section E between 2004 and 2009. After thorough investigation (see Harrison et al., 2010), 39 additional articles are retracted as a result of problems with the data sets or incorrect atom assignments. Full detai