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Bis­[2-(phenethyl­imino­methyl)­phenolato-κ2N,O]copper(II)

✍ Scribed by Akitsu, Takashiro ;Einaga, Yasuaki

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
480 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Cu(C 15 H 14 NO) 2 ], adopts a stepped conformation and displays a square-planar trans-[CuN 2 O 2 ] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the CuÐN and CuÐO bond distances are 2.013 (2) and 1.893 (2) A Ê , respectively, while for the other molecule, these distances are 2.008 (2) and 1.896 (2) A Ê . The extended conformation of the phenethylimine pendant groups results in crystal packing formed by weakly aggregated planar molecules.

📜 SIMILAR VOLUMES

Bis[2-(1-naphthyliminomethyl)phenolato-κ
Bis[2-(1-naphthyliminomethyl)phenolato-κ2N,O]copper(II)
✍ Dong, Jian-Fang ;Li, Lian-Zhi ;Gao, Li-Wei ;Xu, Tao ;Wang, Da-Qi 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 128 KB

In the title complex, [Cu(C 17 H 12 NO) 2 ], the Cu II ion is coordinated by two bidentate ligands in a trans arrangement, forming a CuN 2 O 2 slightly distorted square-planar configuration.