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Bis­[2-(o-tolyl­imino­methyl)­phenolato]copper(II)

✍ Scribed by Zhu, Hai-Liang ;Cheng, Kui ;You, Zhong-Lu ;Li, Yu-Guang

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
320 KB
Volume
61
Category
Article
ISSN
1600-5368

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The title compound, [Cu(C 14 H 13 NO) 2 Cl 2 ], is a mononuclear copper(II) complex of a Schiff base. The Cu II atom is coordinated by two O atoms from two 2-(o-tolyliminomethyl)phenolate ligands, and by two chloride anions, forming a tetrahedral geometry.

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The title compound, [Cu(C 15 H 14 NO) 2 ], adopts a stepped conformation and displays a square-planar trans-[CuN 2 O 2 ] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the CuÐN and CuÐO bond di

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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê R factor = 0.043 wR factor = 0.117 Data-to-parameter ratio = 19.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title centrosymmetric mononuclear copper(II) compound, [Cu(C 14 H 22 N 2 O) 2 ](ClO 4 ) 2 , the Cu II atom is coordinated by two N atoms and two O atoms from two Schiff base ligands. The coordination geometry is slightly distorted square-planar. The disordered perchlorate anions are hydrogen