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Bis{2-[3-(diethyl­amino)­propyl­imino­methyl]­phenolato}copper(II) diperchlorate

✍ Scribed by You, Zhong-Lu ;Xiong, Zhong-Duo ;Zhu, Hai-Liang

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
325 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title centrosymmetric mononuclear copper(II) compound, [Cu(C 14 H 22 N 2 O) 2 ](ClO 4 ) 2 , the Cu II atom is coordinated by two N atoms and two O atoms from two Schiff base ligands. The coordination geometry is slightly distorted square-planar. The disordered perchlorate anions are hydrogen bonded to the cation via NÐHÁ Á ÁO hydrogen bonds.

📜 SIMILAR VOLUMES

Bis­[2-(cyclo­propyl­imino­methyl)­pheno
Bis­[2-(cyclo­propyl­imino­methyl)­phenolato]­zinc(II)
✍ You, Zhong-Lu ;Lin, Yong-Shan ;Liu, Wei-Sheng ;Tan, Min-Yu ;Zhu, Hai-Liang 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 240 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.019 A Ê R factor = 0.055 wR factor = 0.159 Data-to-parameter ratio = 13.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Dibromo­{2-[3-(methyl­amino)propyl­imino
Dibromo­{2-[3-(methyl­amino)propyl­imino­meth­yl]phenolato}zinc(II)
✍ Qiu, Xiao-Yang 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 303 KB

The title compound, [ZnBr~2~(C~11~H~16~N~2~O)], is a mononuclear Schiff base zinc(II) complex. The Zn^II^ atom is four-coordinated by one phenolate O and one imine N atom of the Schiff base ligand, and by two bromide anions, forming a tetrahedral coordination. In the crystal structure, molecules are