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Bis­[2-(quinolin-3-yl­imino­methyl)­phenolato-κ2N,O]copper(II)

✍ Scribed by Akitsu, Takashiro ;Einaga, Yasuaki


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
353 KB
Volume
60
Category
Article
ISSN
1600-5368

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Bis­[2-(phenethyl­imino­methyl)­phenolat
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The title compound, [Cu(C 15 H 14 NO) 2 ], adopts a stepped conformation and displays a square-planar trans-[CuN 2 O 2 ] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the CuÐN and CuÐO bond di

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The crystal structure of the title complex, [Mn(C 9 H 9 NO 2 ) 2 ]Á-0.5H 2 O, contains two Mn IV units related by a twofold rotation axis and linked by intermolecular hydrogen bonds to a water molecule lying on this twofold axis.