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Bis{2-[(2-oxidoeth­yl)imino­meth­yl]phenolato-κ3O,N,O′}manganese(IV) hemihydrate

✍ Scribed by Zhan, Shu-Zhong ;Zhang, Ying-Jun ;Wang, Jian-Ge


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
205 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


The crystal structure of the title complex, [Mn(C 9 H 9 NO 2 ) 2 ]Á-0.5H 2 O, contains two Mn IV units related by a twofold rotation axis and linked by intermolecular hydrogen bonds to a water molecule lying on this twofold axis.


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Dichloro­bis[2-(o-tolyl­imino­meth­yl)ph
✍ Yang, Yu-Min 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 266 KB

The title compound, [Cu(C 14 H 13 NO) 2 Cl 2 ], is a mononuclear copper(II) complex of a Schiff base. The Cu II atom is coordinated by two O atoms from two 2-(o-tolyliminomethyl)phenolate ligands, and by two chloride anions, forming a tetrahedral geometry.