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(OC-6-22)-Bis{2-[1-(2-oxidoethyl­imino)­eth­yl]phenolato-κ3O,N,O′}titanium(IV)

✍ Scribed by Böhme, Uwe ;Günther, Betty

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
116 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Ti(C~10~H~11~NO~2~)~2~], the Ti atom is octahedrally coordinated by two tridentate chelate ligands in a meridional arrangement.

📜 SIMILAR VOLUMES

Bis{2-[(2-oxidoeth­yl)imino­meth­yl]phen
Bis{2-[(2-oxidoeth­yl)imino­meth­yl]phenolato-κ3O,N,O′}manganese(IV) hemihydrate
✍ Zhan, Shu-Zhong ;Zhang, Ying-Jun ;Wang, Jian-Ge 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 205 KB

The crystal structure of the title complex, [Mn(C 9 H 9 NO 2 ) 2 ]Á-0.5H 2 O, contains two Mn IV units related by a twofold rotation axis and linked by intermolecular hydrogen bonds to a water molecule lying on this twofold axis.

Bis[2,4-dichloro-6-(piperidin-1-ylmeth­y
Bis[2,4-dichloro-6-(piperidin-1-ylmeth­yl)phenolato-κ2N,O]copper(II)
✍ Kubono, Koji ;Oshima, Syunichi ;Hirayama, Naoki ;Yokoi, Kunihiko 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 158 KB

In the title compound, [Cu(C 12 H 14 Cl 2 NO) 2 ], the Cu II atom is four-coordinated in a distorted square-planar geometry by two N atoms and two O atoms from two 2,4-dichloro-6-(piperidin-1-ylmethyl)phenolate ligands. The dihedral angle between the N/Cu/O coordination planes is 16.53 (9) .