𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis[2,4-dichloro-6-(piperidin-1-ylmeth­yl)phenolato-κ2N,O]copper(II)

✍ Scribed by Kubono, Koji ;Oshima, Syunichi ;Hirayama, Naoki ;Yokoi, Kunihiko

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
158 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, [Cu(C 12 H 14 Cl 2 NO) 2 ], the Cu II atom is four-coordinated in a distorted square-planar geometry by two N atoms and two O atoms from two 2,4-dichloro-6-(piperidin-1-ylmethyl)phenolate ligands. The dihedral angle between the N/Cu/O coordination planes is 16.53 (9) .

📜 SIMILAR VOLUMES

2,4-Dichloro-6-(piperidin-1-ylmeth­yl)ph
2,4-Dichloro-6-(piperidin-1-ylmeth­yl)phenol
✍ Kubono, Koji ;Oshima, Syunichi ;Hirayama, Naoki ;Yokoi, Kunihiko 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 263 KB

In the title compound, C 12 H 15 Cl 2 NO, the piperidine ring adopts a chair conformation. An intramolecular O-HÁ Á ÁN hydrogen bond is observed. The packing of the molecules in the crystal structure is stabilized byinteractions and ClÁ Á ÁCl contacts.

Dichloro­{4-chloro-2-[2-(diethyl­ammonio
Dichloro­{4-chloro-2-[2-(diethyl­ammonio)­ethyl­iminometh­yl]phenolato-κ2N,O}copper(II)
✍ Wang, Qing ;Qiu, Xiao-Yang 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 130 KB

The title compound, [CuCl 2 (C 13 H 19 ClN 2 O)], is a mononuclear copper(II) complex. The Cu II ion is four-coordinated by the phenolate O and the imine N atoms of the Schiff base ligand, and by two Cl atoms, forming a distorted tetrahedral geometry.

Bis[2-(1-naphthyliminomethyl)phenolato-κ
Bis[2-(1-naphthyliminomethyl)phenolato-κ2N,O]copper(II)
✍ Dong, Jian-Fang ;Li, Lian-Zhi ;Gao, Li-Wei ;Xu, Tao ;Wang, Da-Qi 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 128 KB

In the title complex, [Cu(C 17 H 12 NO) 2 ], the Cu II ion is coordinated by two bidentate ligands in a trans arrangement, forming a CuN 2 O 2 slightly distorted square-planar configuration.

Dichloro­bis[2-(o-tolyl­imino­meth­yl)ph
Dichloro­bis[2-(o-tolyl­imino­meth­yl)phenolato]copper(II)
✍ Yang, Yu-Min 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 266 KB

The title compound, [Cu(C 14 H 13 NO) 2 Cl 2 ], is a mononuclear copper(II) complex of a Schiff base. The Cu II atom is coordinated by two O atoms from two 2-(o-tolyliminomethyl)phenolate ligands, and by two chloride anions, forming a tetrahedral geometry.